#plasmonics
Closing the gap: On the road to terahertz electronics
Asymmetric plasmonic antennas deliver femtosecond pulses for fast optoelectronics
A team headed by the TUM physicists Alexander Holleitner and Reinhard Kienberger has succeeded for the first time in generating ultrashort electric pulses on a chip using metal antennas only a few nanometers in size, then running the signals a few millimeters above the surface and reading them in again a controlled manner.
Classical electronics allows frequencies up to around 100 gigahertz. Optoelectronics uses electromagnetic phenomena starting at 10 terahertz. This range in between is referred to as the terahertz gap, since components for signal generation, conversion and detection have been extremely difficult to implement.
The TUM physicists Alexander Holleitner and Reinhard Kienberger succeeded in generating electric pulses in the frequency range up to 10 terahertz using tiny, so-called plasmonic antennas and run them over a chip. Researchers call antennas plasmonic if, because of their shape, they amplify the light intensity at the metal surfaces.
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Light makes Rice U. catalyst more effective: Halas lab details plasmonic effect that allows catalyst to work at lower energy
Rice University nanoscientists have demonstrated a new catalyst that can convert ammonia into hydrogen fuel at ambient pressure using only light energy, mainly due to a plasmonic effect that makes the catalyst more efficient.
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A study from Rice’s Laboratory for Nanophotonics (LANP) in this week’s issue of Science describes the new catalytic nanoparticles, which are made mostly of copper with trace amounts of ruthenium metal. Tests showed the catalyst benefited from a light-induced electronic process that significantly lowered the “activation barrier,” or minimum energy needed, for the ruthenium to break apart ammonia molecules.
The research comes as governments and industry are investing billions of dollars to develop infrastructure and markets for carbon-free liquid ammonia fuel that will not contribute to greenhouse warming. But the researchers say the plasmonic effect could have implications beyond the “ammonia economy.”
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Lighting the way for new materials
What happens when gold and silver just don’t cut it anymore? You turn to metallic alloys, which are what Army researchers are using to develop new designer materials with a broad range of capabilities for our Soldiers.
This is exactly what scientists Dr. David Baker and Dr. Joshua McClure from the U.S. Army Research Laboratory are doing to lighten the load and enhance the power of Soldier devices used on the battlefield.
Their research, conducted in collaboration with Prof. Marina Leite and Dr. Chen Gong at the University of Maryland and Prof. Alexandre Rocha at the Universidade Estadual Paulista in Brazil, was recently featured on the cover of the Sept. 4 issue of Advanced Optical Materials.
The research paper, “Band Structure Engineering by Alloying for Photonics,” focuses on control of the optical and plasmonic properties of gold and silver alloys by changing alloy chemical composition.
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Tripling the efficiency of solar-based hydrogen fuel generation with metallic nanostructures that slow down light
Hydrogen gas, an important synthetic feedstock, is poised to play a key role in renewable energy technology; however, its credentials are undermined because most is currently sourced from fossil fuels, such as natural gas. A KAUST team has now found a more sustainable route to hydrogen fuel production using chaotic, light-trapping materials that mimic natural photosynthetic water splitting.
The complex enzymes inside plants are impractical to manufacture, so researchers have developed photocatalysts that employ high-energy, hot electrons to cleave water molecules into hydrogen and oxygen gas. Recently, nanostructured metals that convert solar electrons into intense, wave-like plasmon resonances have attracted interest for hydrogen production. The high-speed metal plasmons help transfer carriers to catalytic sites before they relax and reduce catalytic efficiency.
Getting metal nanoparticles to respond to the entire broadband spectrum of visible light is challenging. “Plasmonic systems have specific geometries that trap light only at characteristic frequencies,” explains Andrea Fratalocchi, who led the research. “Some approaches try to combine multiple nanostructures to soak up more colors, but these absorptions take place at different spatial locations so the sun’s energy is not harvested very efficiently.”
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