As silicon-based semiconductors reach their performance limits, gallium nitride (GaN) is becoming the next go-to material to advance light-emitting diode (LED) technologies, high-frequency transistors and photovoltaic devices. Holding GaN back, however, is its high numbers of defects.
This material degradation is due to dislocations—when atoms become displaced in the crystal lattice structure. When multiple dislocations simultaneously move from shear force, bonds along the lattice planes stretch and eventually break. As the atoms rearrange themselves to reform their bonds, some planes stay intact while others become permanently deformed, with only half planes in place. If the shear force is great enough, the dislocation will end up along the edge of the material.
Layering GaN on substrates of different materials makes the problem that much worse because the lattice structures typically don’t align. This is why expanding our understanding of how GaN defects form at the atomic level could improve the performance of the devices made using this material.
A team of researchers has taken a significant step toward this goal by examining and determining six core configurations of the GaN lattice. They presented their findings in the Journal of Applied Physics.
Using powerful computer simulations, researchers from Brown University have identified a material with a higher melting point than any known substance.
The computations, described in the journal Physical Review B (Rapid Communications), showed that a material made with just the right amounts of hafnium, nitrogen, and carbon would have a melting point of more than 4,400 kelvins (7,460 degrees Fahrenheit). That’s about two-thirds the temperature at the surface of the sun, and 200 kelvins higher than the highest melting point ever recorded experimentally.
The experimental record-holder is a substance made from the elements hafnium, tantalum, and carbon (Hf-Ta-C). But these new calculations suggest that an optimal composition of hafnium, nitrogen, and carbon – HfN0.38C0.51 – is a promising candidate to set a new mark. The next step, which the researchers are undertaking now, is to synthesize material and corroborate the findings in the lab.
“The advantage of starting with the computational approach is we can try lots of different combinations very cheaply and find ones that might be worth experimenting with in the lab,” said Axel van de Walle, associate professor of engineering and co-author of the study with postdoctoral researcher Qijun Hong. “Otherwise we’d just be shooting in the dark. Now we know we have something that’s worth a try.”
Chemists are working to synthesize the next generation of super materials for high-performance electronics, solar cells, photodetectors and quantum computers. While they have made progress with compound materials, they have not yet succeeded in developing unaltered or “freestanding” materials for such devices, according to a review published in the journal Science and Technology of Advanced Materials.
Graphene is a carbon material derived from graphite, the same type of material found in pencils, but it is arranged in a one-atom-thin honeycomb lattice. Discovered in 2004, graphene’s two-dimensional arrangement gives it “extraordinary” properties, including extreme strength and “marvelously high” electron conductivity.
However, the tight lattice lacks a semiconducting bandgap, which is essential for electronic devices. Therefore, scientists have been hunting for alternative materials that have bandgaps, but still have a graphene-like structure.
Much focus has been placed on graphene quantum dots, which are small segments of graphene, about 10 to 100 nm carbon hexagons across and less than 30 atomic sheets thick. To make the dots behave more like 2-D graphene, research teams have added other molecules to change the structure and function of the material.
Nano-sized diamonds with certain defects are assetsfor people who study light.
Marko Loncar, an NSF-funded electrical engineer at Harvard School of Engineering and Applied Sciences, creates tiny structures out of diamonds and other elements to manipulate how light and matter interact on the nanoscale.
For instance, Loncar, who is part of the Nanoscale Interdisciplinary Research Team, uses diamond posts in a silver substrate as the scalable platform to enhance single photon emission by nitrogen vacancy centers in diamond.
Nitrogen vacancy centers are defects formed in diamonds that allow for the precise manipulation of absorbed photons and emitted light.
You may not want a flawed diamond on your finger, but it’s the defect that makes things like quantum computing possible.
An exotic material called gallium nitride (GaN) is poised to become the next semiconductor for power electronics, enabling much higher efficiency than silicon. In 2013, the Department of Energy (DOE) dedicated approximately half of a $140 million research institute for power electronics to GaN…
One of the most critical issues the United States faces today is preventing terrorists from smuggling nuclear weapons into its ports. To this end, the U.S. Security and Accountability for Every Port Act mandates that all overseas cargo containers be scanned for possible nuclear materials or weapons.
Detecting neutron signals is an effective method to identify nuclear weapons and special nuclear materials. Helium-3 gas is used within detectors deployed in ports for this purpose.
The catch? While helium-3 gas works well for neutron detection, it’s extremely rare on Earth. Intense demand for helium-3 gas detectors has nearly depleted the supply, most of which was generated during the period of nuclear weapons production during the past 50 years. It isn’t easy to reproduce, and the scarcity of helium-3 gas has caused its cost to skyrocket recently – making it impossible to deploy enough neutron detectors to fulfill the requirement to scan all incoming overseas cargo containers.
Helium-4 is a more abundant form of helium gas, which is much less expensive, but can’t be used for neutron detection because it doesn’t interact with neutrons.
What’s creating these long glowing streaks in the sky? No one is sure! They’re known as Strong Thermal Emission Velocity Enhancements (STEVEs). Strong, luminous light-purple sky ribbons that may resemble regular auroras, but recent research reveals significant differences. A STEVE’s great length and unusual colors, when measured precisely, indicate that it may be related to a subauroral ion drift (SAID), a supersonic river of hot atmospheric ions thought previously to be invisible. The featured wide-angle composite image shows a STEVE in a dark sky above Childs Lake, Manitoba, Canada, crossing in front of the central band of our Milky Way Galaxy. Image Credit: NASA, Krista Trinder
